Study of Distribution Coefficient of 90Sr on Citumbuk Bentonite and Sukaramai Kaolinite

Budi Setiawan, Heni Suseno

DOI: http://dx.doi.org/10.55981/eksplorium.2017.3056

Abstract


ABSTRACT

The study of distribution coefficient of strontium on bentonite and kaolinite samples, collected from Citumbuk, Bogor and Sukaramai, Padang, has been investigated under batch experiments. The sorption ratio was determined as a function of time, ionic strength and Sr concentration in the solution. The strontium wasextensively absorbed in the samples, with Kd values of 13,700 and 1,600 mL/g for bentonite and kaolinite samples respectively. The other results showed that ionic strength of the solution and initial concentration of Sr have given an effect to 90Sr sorption onto samples.

ABSTRAK

Studi tentang koefisien distribusi dari stronsium pada sampel bentonit dan kaolin yang diambil dari lokasi Citumbuk, Bogor dan Sukaramai, Padang, telah diteliti secara catu. Rasio penyerapan ditentukan sebagai fungsi waktu, kekuatan ionic dan konsentrasi Sr di larutan. Stronsium telah terserap dengan baik pada sampel, dengan nilai Kd adalah 13.700 dan 1.600 mL/g masing-masing untuk sampel bentonite dan kaolin. Hasil lainnya menunjukkan bahwa kekuatan ionik dan konsentrasi awal Sr di larutan telah memberikan pengaruh pada penyerapan 90Sr ke dalam sampel.




Keywords


buffer materials; 90Sr; Kd

Full Text:

PDF

References


[1] M. J. O'Hara, S. R. Burge, J. W. Grate, “Automated Radioanalytical System For The Determination of Sr-90 In Environmental Water Samples By Y-90 Cherenkov Radiation Counting”, Analytical Chemistry, 81, pp.1228-1237, 2009.

[2] B. Setiawan, “Sorption of Strontium Onto Clay Materials From Sumedangas One of Potential Site For Radioactive Waste Disposal Facility”, J. Technology of Waste Manag. vol. 15, no.1, pp.67-72, 2012. – in Indonesian.

[3] B. Setiawan, Y. Dani, N. Arofah, “Sorption Characteristics of 137Cs and 90Sr into Rembang and Sumedang Soils”, Indones. J.Chemistry., 16 (3), pp.277-282, 2016.

[4] B. Setiawan, O. Mila, Safni, “Interaction of Sr-90 With Site Candidate Soil For Demonstration Disposal Facility at Serpong”, AIP Conf. Proc. 1589, pp.325-328, 2014, Bandung doi:10.1063/1.4868811.

[5] Y. Fujikawa, M. Fukui, “Radionuclide Sorption to Rocks And Minerals: Effects of pHand Inorganic Anions. Part 1. Sorption of Cesium, Cobalt, Strontium and Manganese”, Radiochim.Acta, 76, pp.153-162, 1997.

[6] R. M. Cornell, “Adsorption of Cesium on Minerals: A Review”, J.Radioanal.Nucl.Chem., 171, pp.483-500, 1993.

[7] S. Sadasivam, and S. M. Rao, “Characterization of Silver–Kaolinite (AgK): An Adsorbent for Long-Lived 129I Species”, SpringerPlus, 5, pp.142, 2016. doi: 10.1186/s40064-016-1855-8.

[8] Y. F. Xu, D. Sun, Y. Yao, “Surface Fractal Dimensionof Bentonite and Its Application to Determination of Swelling Properties”, Chaos Solitons Fractals vol.19, no.2, pp.347–356, 2004.

[9] S.J. Pendleton, The Migration of Radioactive Caesium and Strontium Through a Bentonite-like Clay, Doctoral Thesis, Loughborough University, 2014.

[10] M.L. Zhang, A. Ren, D. Shao, X. Wang, “Effect of Fulvic Acid and Ionic Strength on The Sorption of Radiostrontiumon Chinese Calcareous Soil and Its Solid Components”, J. Radioanal. Nucl. Chem., vol. 268, no. 1, pp.33–36, 2006.

[11] R. D. Rani and P. Sasidhar, “Geochemicaland Thermodynamic Aspects of Sorption of Strontium on Kaolinite Dominated Clay Samples at Kalpakkam”, Environ Earth Sci 65, pp.1265, 2012.

[12] B. Yıldız, H. N. Erten, M. Kıs¸, “The Sorption Behavior of Cs+ Ion on Clay Minerals and Zeolite in Radioactive Waste Management: Sorption Kinetics and Thermodynamics”, J. Radioanal Nucl Chem288, pp.475–483, 2011.

[13] M. Galambos, J. Kufcakova, O. Rosskopfova, P. Rajec, “Adsorption of Cesium and Strontiumon Natrified Bentonites”, J. Radioanal Nucl Chem, 283, pp.803–813, 2010.


Refbacks

  • There are currently no refbacks.


Bookmark and Share


Google Scholar Logo SINTA Logo Logo GARUDA

Copyright EKSPLORIUM: Buletin Pusat Pengembangan Bahan Galian Nuklir (e-ISSN 2503-426x p-ISSN 0854-1418)

National Research and Innovation Agency (BRIN), KA. B.J. Habibie, Jl. M.H. Thamrin No.8, Jakarta, 10340, Indonesia.