UNIQUE CONFORMATION OF RH(I) PILLAR COMPLEXES IMMOBILIZED ON TAENIOLITE
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(1) Research Center for Chemistry of Indonesian Institute of Sciences Kawasan Puspiptek, Serpong15314, Tangerang
(2) Department of Applied Chemistry and Biotechnology of Chiba University 1-33, Yayoi-cho, 1nage-ku, Chiba-shi, 263-8522 Japan
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Abstract
UNIQUE CONFORMATION OF RH(I) PILLAR COMPLEXES IMMOBILIZED ON TAENIOLITE. Rhodiumpillar complex with chiral diamine ligands, Rh-Cn-(-)-CHDA, were synthesized and intercalated with various loading amounts in the range of 19 - 26%CEC, Cation Exchange Capacity (CEC) into Lithium Taeniolite (LiTN) These pillared catalysts (Rh-Cn-(-)-CHDA/TN) were characterized by XRD, elementary analysis, and FT-IR. Results of XRD analysis showed that the clearance space of the catalyst interlayer increased proportionally with the alkyl chain length of the ligandwith the slopeof 0.14 nm/CH2.
Keywords
Rh(I) pillar complex, Taeniolite
DOI: 10.17146/jusami.2011.13.1.5392